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Thermo Scientific Alfa Aesar 1,1'-Bis(diphenylphosphino)ferrocene, 97%, Thermo Scientific Chemicals


Overview
Code: NEW

Additional Details:
Additional Details: CAS Number: 12150-46-8 Weight: 0.00100kg Transport: UN number : 3467 Chem class : 6.1 Pack group : III


Quantity 1 g

Disclaimers: RUO – Research Use Only

Product Code. 11454657

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  • Description and Specification
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Description and Specification

Chemical Identifiers

CAS 12150-46-8
Molecular Formula C34H28FeP2
Molecular Weight (g/mol) 554.39
MDL Number MFCD00001422
InChI Key KZPYGQFFRCFCPP-UHFFFAOYSA-N
IUPAC Name λ²-iron(2+) bis(1-(diphenylphosphanyl)cyclopenta-2,4-dien-1-ide)
SMILES [Fe].c1ccc(c1)P(C1=CC=CC=C1)C1=CC=CC=C1.c1ccc(c1)P(C1=CC=CC=C1)C1=CC=CC=C1

Specification

Chemical Name or Material 1, 1'-Bis(diphenylphosphino)ferrocene
CAS 12150-46-8
Melting Point ∽182°C (decomposition)
Assay Percent Range 0.97
Molecular Formula C34H28FeP2
MDL Number MFCD00001422
Quantity 1 g
Sensitivity Air sensitive
Solubility Information Soluble in chloroform,dichloromethane,alcohol and pentane. Insoluble in water.
InChI Key KZPYGQFFRCFCPP-UHFFFAOYSA-N
SMILES [Fe].c1ccc(c1)P(C1=CC=CC=C1)C1=CC=CC=C1.c1ccc(c1)P(C1=CC=CC=C1)C1=CC=CC=C1
IUPAC Name λ²-iron(2+) bis(1-(diphenylphosphanyl)cyclopenta-2,4-dien-1-ide)
Molecular Weight (g/mol) 554.39
Formula Weight 554.4
Percent Purity 97%

Applications
1,1′-Bis(diphenylphosphino)ferrocene acts as a ligand in homogeneous catalysis. It is used as a ligand for ruthenium-catalyzed greener amine synthesis from amines and alcohols by hydrogen-borrowing. It is also employed as a ligand for Buchwald-Hartwig cross coupling. Further, it is used in the synthesis of coordination compound as well as the formation of complexes with various metals such as palladium chloride. In addition to this, it serves as a reagent for palladium-catalyzed coupling reactions and also plays an important role in Suzuki reaction.

Solubility
Soluble in chloroform, dichloromethane, alcohol and pentane. Insoluble in water.

Notes
Air sensitive. Store in a cool place. Incompatible with strong oxidizing agents.

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Documentation

Technical documents